We introduce a paradigm-"hydricity"-that involves the coproduction of hydrogen and electricity from solar thermal energy and their judicious use to enable a sustainable economy. We identify and implement synergistic integrations while improving each of the two individual processes. When the proposed integrated process is operated in a standalone, solely power production mode, the resulting solar water power cycle can generate electricity with unprecedented efficiencies of 40-46%. Similarly, in standalone hydrogen mode, pressurized hydrogen is produced at efficiencies approaching ∼50%. In the coproduction mode, the coproduced hydrogen is stored for uninterrupted solar power production. When sunlight is unavailable, we envision that the stored hydrogen is used in a "turbine"-based hydrogen water power (H 2 WP) cycle with the calculated hydrogen-toelectricity efficiency of 65-70%, which is comparable to the fuel cell efficiencies. The H 2 WP cycle uses much of the same equipment as the solar water power cycle, reducing capital outlays. The overall sun-toelectricity efficiency of the hydricity process, averaged over a 24-h cycle, is shown to approach ∼35%, which is nearly the efficiency attained by using the best multijunction photovoltaic cells along with batteries. In comparison, our proposed process has the following advantages: (i) It stores energy thermochemically with a two-to threefold higher density, (ii) coproduced hydrogen has alternate uses in transportation/chemical/petrochemical industries, and (iii) unlike batteries, the stored energy does not discharge over time and the storage medium does not degrade with repeated uses. solar | electricity | hydrogen | solar thermal power | process synthesis D iminishing fossil fuel resources and increasing atmospheric greenhouse gas levels raise the ever-growing interest in developing and implementing renewable energy conversion technologies and strategies to meet society's energy needs (1-5). Among renewable energy sources, solar energy is prominent for its abundance. To put it into perspective, in 1.5 h 6.5 × 10 20 J of solar energy reaches the earth, which is more than the primary energy consumed cumulatively by humans on the planet in 1 y (∼5.4 × 10 20 J in 2013) (4, 6). However, harnessing solar energy for uninterruptable energy supply remains a challenge because it requires conversion systems to be integrated with efficient storage systems to overcome the inherent intermittency and uneven geographical distribution of solar irradiation.Here, we introduce the concept of "hydricity" to address this challenge. We propose solar thermal coproduction of hydrogen and electricity and their subsequent synergistic use to support a sustainable economy. Hydricity not only leads to efficient production of solar electricity but also opens up many more possibilities: a sustainability roadmap. In the subsequent sections, we present an example hydricity process to supply uninterruptable electricity round-the-clock at a constant power rate with a calculated overall sun-to-electr...