The word lignin is derived from the Latin word lignum meaning wood. It is one of the main components of all vascular plants and the second most abundant polymer in nature. This article describes the current understanding of the structure of this complex natural polymer. The number and types of different chemical bonds present in lignin are discussed, as are the ways in which different lignins are identified and their distributions determined in plant tissues. Means for isolating lignin from wood are described, and the chemical and physical properties of the resulting lignins are reviewed. The various chemical and instrumental methods for characterizing isolated lignins are also discussed. The article concludes with a review of commercial lignin products including a discussion of producers, production methods, modification reactions, and the many industries in which lignins are used.