Gaseous thallium(I) metaborate and thallium(I) aluminum fluoride

Abstract

Mlile all the thallium (I) halides have been studied, 1 only two gaseous ternary compounds of monovalent thallium, thallium (I) nitrate 2 and thallium (I) sulfate, 3 have been reported so far. The purpose of this work was to extend the range of known gaseou5 ternary compounds of thallium (I) and to compare their mass spectrometric behavior to that of the corresponding alkali compm.mds. We have therefore examined the vapors above thallium (I) retaborate and an equimolar mixture of thallium (I) fluoride and aluminum fluoride.

Thermodynamic properties and structure of gaseous metaborates

“…In [68][69][70][71], it was demonstrated that the behavior of indium and thallium metaborates upon vaporization is…”