2024
DOI: 10.1021/jacs.4c06487
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GaSI: A Wide-Gap Non-centrosymmetric Helical Crystal

Kaitlyn G. Dold,
Dmitri Leo Mesoza Cordova,
Sirisak Singsen
et al.

Abstract: The complex non-centrosymmetric and chiral nature of helical structures endow materials that possess such motifs with unusual properties. However, despite their ubiquity in biological and organic systems, there is a severe lack of inorganic crystals that display helicity in extended lattices, where these unusual properties are expected to be most pronounced. Here, we report a new inorganic helical structure, gallium sulfur iodide (GaSI), within the exfoliable class of III–VI–VII (1:1:1) one-dimensional (1D) va… Show more

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