Iron/carbon (Fe/C) composites efficiently
remove Cr(VI) because
of synergistic adsorption and reduction effects. This study uses harmful
algal bloom (HAB) biomass and ferric ammonium citrate (FAC) or ferric
nitrate as precursors for preparing Fe/Cs with a one-pot synthesis.
The investigation uniquely differentiates material and performance
impacts associated with two iron loading approaches, bioaccumulation
(metal uptake by living algae), and biosorption (metal deposition
onto dry algae). As-prepared Fe/Cs are up to 70% mesoporous with iron
loading reaching 8.3 wt %. Uniformly dispersed nanoparticles (20–50
nm) are observed in all Fe/Cs, and microscale particles are present
on the surface of biosorption samples due to sintering. Fe3O4 is the dominant iron species in Fe (NO3)3 added samples, while Fe0 dominates samples prepared
with FAC, attributed to the reducing atmosphere generated during FAC
pyrolysis. Up to 4.0 wt % nitrogen doping is achieved, from nitrogen
in HAB biomass and iron precursors. Fe/Cs remove up to 165 mg/g Cr(VI)
at pH = 2 and 73 mg/g Cr(VI) at pH = 6, with rapid kinetics. Magnetic
properties (>16 emu/g) from reduced iron nanoparticles facilitate
Fe/C separation and reuse, and samples maintain 73–82% of their
removal capacity after five removal/recovery cycles. This work is
important because it converts HAB biomass waste into functional materials
with value in environmental applications.