2016
DOI: 10.1007/s13361-016-1430-0
|View full text |Cite
|
Sign up to set email alerts
|

GC-MS Study of Mono- and Bishaloethylphosphonates Related to Schedule 2.B.04 of the Chemical Weapons Convention: The Discovery of a New Intramolecular Halogen Transfer

Abstract: . Second, to study the synergistic effect of halogen and silicon atoms in molecules undergoing mass spectrometry. Fragmentation patterns of trimethylsilyl derivatives of HAPs were found to depend on the nature of the halogen atom; this was in agreement with DFT-calculations. The data suggest that a novel intramolecular halogen transfer takes place during the fragmentation process.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2016
2016
2018
2018

Publication Types

Select...
4

Relationship

0
4

Authors

Journals

citations
Cited by 4 publications
(1 citation statement)
references
References 38 publications
0
1
0
Order By: Relevance
“…On the other hand, such intramolecular transfers are very interesting from the gas phase ion chemistry point of view; therefore, there is a number of examples of detailed studies of such processes. The examples involve transfer of such moieties as amino, halogen, methoxy, benzyl, tosyl, trimethylsilyl, oxygen, alkyl, and hydroxyl, and, as expected, most examples involve transfer of methyl group …”
Section: Introductionmentioning
confidence: 65%
“…On the other hand, such intramolecular transfers are very interesting from the gas phase ion chemistry point of view; therefore, there is a number of examples of detailed studies of such processes. The examples involve transfer of such moieties as amino, halogen, methoxy, benzyl, tosyl, trimethylsilyl, oxygen, alkyl, and hydroxyl, and, as expected, most examples involve transfer of methyl group …”
Section: Introductionmentioning
confidence: 65%