Metal–organic frameworks (MOFs) are ideal sacrificial
templates
and precursors with specialized micro- and nanostructures. In this
paper, bimetallic MOFs-derived Fe2O3/In2O3 composites were proposed for detecting triethylamine
(TEA) gas with high sensitivity and low working temperature by a simple
one-step oil bath method. The samples were analyzed by XRD, SEM, TEM,
and XPS for structural morphology and chemical state, and their gas
performance was investigated. The findings demonstrate that Fe2O3/In2O3 nanotubes exhibit
remarkable sensitivity to TEA gas. The response value to 5 ppm of
TEA gas is 6250 at 100 °C, which is 11.4 times higher than that
of In2O3. The enhanced sensing performance can
be attributed to the generation of additional chemical absorbed oxygen
and the formation of heterojunctions, as evidenced by experimental
and density functional theory (DFT) calculations.