Synthetic polymers, such as polyacrylamide (PAM), and biochar are generally used as soil amendments to improve soil properties. This paper explores a laboratory column experiment conducted to investigate the effects of biochar (pyrolysis at 400–450 °C) and polymers, with different application rates, on the hydro-physical properties of sandy soil. The experiment evaluated four rates each of biochar (0.0% (C), 2% (B1), 4% (B2), 6% (B3) and 8% (B4)) and polymers (0.0% (C), 0.2% (P1), 0.4% (P2), 0.6% (P3), and 0.8%(P4)), as well as a mixture of them. The infiltration rate decreased significantly when a mixture of biochar and polymers was adopted. B1 showed a decrease of 32.73% while a mixture of 8% (B4) and (0.8%) P4 exhibited a decrease of 57.31%. The polymers increased the infiltration rate at low concentrations (P1 and P2) and reduced it at high concentrations (P3 and P4). The cumulative evaporation decreased significantly for most treatments. B1 recorded the highest decrease in cumulative evaporation with a percentage decrease of 31.9%. The highest decrease in hydraulic conductivity (Ks) was for B1. However, the mixture of B4 and P4 resulted in the highest increase in soil moisture content at field capacity compared to the control and other treatments. P4 and the mixture of B2 and P2 showed significant (p < 0.05) increases in the percentage of stable aggregate (SA) in fraction size (0.25–0.125 mm). Although the mixture of B4 and P4 had the highest increase in soil moisture content, this study recommends using the B1 treatment on sandy soil in arid environments due to its strong hydro-physical properties and affordability.