1989
DOI: 10.1021/j100338a045
|View full text |Cite
|
Sign up to set email alerts
|

Geminate recombination kinetics of triplet radical pairs in glycerol: magnetic field effect

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

3
55
0

Year Published

1989
1989
2020
2020

Publication Types

Select...
4
2

Relationship

0
6

Authors

Journals

citations
Cited by 52 publications
(58 citation statements)
references
References 0 publications
3
55
0
Order By: Relevance
“…Characteristics of E from Dow are described in elsewhere. [12][13][14][15][16] Films were cast form solutions of B and a polymer E in chloroform on a cellophane support. The thickness of the prepared solid films was 100 μm and a concentration of B of 0.1 M. For more details on films preparation see ref.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…Characteristics of E from Dow are described in elsewhere. [12][13][14][15][16] Films were cast form solutions of B and a polymer E in chloroform on a cellophane support. The thickness of the prepared solid films was 100 μm and a concentration of B of 0.1 M. For more details on films preparation see ref.…”
Section: Methodsmentioning
confidence: 99%
“…[10][11][12] Polymers obviously decrease diffusivity of low MW species (molecules, free radicals) similar to a decrease of diffusion rates by viscous liquids. [2][3][4][5][6][10][11][12][13][14] In the present work we continued our research, and studied temperature effect on kinetics of recombination of G-and of F-pairs. As a polymer media, we selected soft rubbery polymer.…”
Section: Introductionmentioning
confidence: 99%
“…In other words, a geminate recombination proceeds considerably longer than expected. 12,13,15 Not only does the temperature/viscosity of media affect F; another possible way that F increases in a system with the same reagents was observed in Ref. 16.…”
Section: Cage Effect Under Photodissociationmentioning
confidence: 87%
“…An increase in viscosity leads to an increase in a RP lifetime and slows down molecular diffusivity: these features allow S-T transitions to occur in the RP, and geminate recombination of free radicals is expected to occur, increasing the cage effect F. 11 Experimental measurements demonstrate that the cage effect F increases with an increase in solvent viscosity. [11][12][13] An increase of media viscosity, which usually takes place upon polymerization, also results in a decrease in the rate of polymerization as the process approaches completion. 14 Cage effect dynamics or kinetics of geminate recombination was observed for the first time under photodissociation of a CÀC dimer of aromatic radicals in a viscous media.…”
Section: Cage Effect Under Photodissociationmentioning
confidence: 99%
See 1 more Smart Citation