Multimedia means, combination of text, audio, still images, animation, video and interactivity content forms delivered electronically. E-learning is a process and e-content is a product. The objectives of the study are to find out the significant relationship between the college of education teachers' perception towards multimedia technology on the basis of gender wise, locality wise, marital wise, subject wise, technical skill wise, experience wise and possessing degree wise. Evaluation of Multimedia Perception scale (EMPS) developed by the investigator with a reliability of 0.89 and it collected 350 teachers from Tamil Nadu State of Indian Context. From the analysis, there are no significant differences between the perceptions of multimedia technology in terms of gender, locality and marital status. The same perception was rejected on the basis of subject, technical skills, higher degree level and their experiences. The quality of learning depends not only on the form of how the process is carried out but also on what content is taught and how the content is presented.