We present the first results of our ongoing chemical study of carbon stars in the Local Group of galaxies. We used spectra obtained with UVES at the 8.2 m Kueyen-VLT telescope and a new grid of spherical model atmospheres for cool carbon-rich stars which include polyatomic opacities, to perform a full chemical analysis of one carbon star, BMB-B 30, in the Small Magellanic Cloud (SMC) and two, IGI95-C1 and IGI95-C3, in the Sagittarius Dwarf Spheroidal (Sgr dSph) galaxy. Our main goal is to test the dependence on the stellar metallicity of the s-process nucleosynthesis and mixing mechanism occurring in AGB stars. For these three stars, we find important s-element enhancements with respect to the mean metallicity ([M/H]), namely [s/M] ≈ +1.0, similar to the figure found in galactic AGB stars of similar metallicity. The abundance ratios derived between elements belonging to the first and second s-process abundance peaks, corresponding to nuclei with a magic number of neutrons N = 50 (88Sr, 89Y, 90Zr) and N = 82 (138Ba, 139La, 140Ce, 141Pr), agree remarkably well with the theoretical predictions of low mass (M < 3 M ) metal-poor AGB nucleosynthesis models where the main source of neutrons is the 13 C(α, n) 16 O reaction activated during the long interpulse phase, in a small pocket located within the He-rich intershell. The derived C/O and 12 C/ 13 C ratios are, however, more difficult to reconcile with theoretical expectations. Possible explanations, like the extrinsic origin of the composition of these carbon stars or the operation of a non-standard mixing process during the AGB phase (such as the cool bottom process), are discussed on the basis of the collected observational constraints.