We present the inscription and characterization of fiber Bragg gratings (FBGs) in polypropylene coreless cylindrical fibers. Polypropylene material offers several advantages, such as strong chemical resistance, biocompatibility, and high tensibility. Therefore, polypropylene FBGs can be useful for sensing in chemically aggressive environments and in biomedical applications. The coreless, cylindrical polypropylene waveguides used in these experiments had a diameter of 150 μm, typical length up to 20 cm, and a refractive index of 1.49. The inscription was performed in the 1550 nm transparency window by using a phase mask technique and 193 nm excimer laser radiation. Inscribed FBGs demonstrated complex multi-peak reflection spectra due to highly multi-mode nature of the polypropylene waveguides. Due to a high attenuation of the polypropylene, the maximum waveguide FBG interrogation length -in reflection-was 6 cm. Gratings characterization demonstrated a strain sensitivity of 0.9 pm/με, a temperature sensitivity of -60.4 pm/℃ and humidityinsensitive behavior.