1984
DOI: 10.1016/0032-3950(84)90244-2
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General nature of the effect of molecular weight on the composition of a copolymer on homogeneous radical copolymerization

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Cited by 7 publications
(3 citation statements)
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“…In a conventional process, a high polymer is formed at very low conversion and the polymer composition is determined at low conversion. It was previously reported that reactivity ratios depend strongly on polymerization degree . Such an effect may originate in different chemoselectivities of initiating and propagating species.…”
Section: Resultsmentioning
confidence: 99%
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“…In a conventional process, a high polymer is formed at very low conversion and the polymer composition is determined at low conversion. It was previously reported that reactivity ratios depend strongly on polymerization degree . Such an effect may originate in different chemoselectivities of initiating and propagating species.…”
Section: Resultsmentioning
confidence: 99%
“…It was previously reported that reactivity ratios depend strongly on polymerization degree. 53 Such an effect may originate in different chemoselectivities of initiating and propagating species.…”
Section: Resultsmentioning
confidence: 99%
“…Semchikov [12][13] has found out compositional inhomogeneity of copolymers that has been explained by a variation of K during the macromolecule growth. If the copolymerization is carried out under conditions allowing profound chain transfer and to low conversion, the analysis of the prepared oligomers would give the real MRR's.…”
Section: The Vmp-pmp Equilibriummentioning
confidence: 99%