A series of test experiments on three different Si-based neutron detectors, namely a 1-d 128 channel, 0.5 mm space resolution Si microstrip sensor coupled to natural Gd converter, a medium size ∼ 1 cm 2 PIN diode coupled to n Gd 2 O 3 or 157 Gd 2 O 3 converters, and a SiPM photomultiplier coupled to neutron scintillators, are presented to show the performances of this class of devices for thermal neutron detection. A pulse shape analysis method, designed to improve the performance of these devices by an optimized discrimination of the neutron signals from noise and background radiation, is proposed, described and tested. This study is aimed to real time applications and single event storage of the neutron information in time of flight instrumentation.