We determine invariants like the Smith normal form and the determinant for certain integral matrices which arise from the character tables of the symmetric groups S n and their double covers. In particular, we give a simple computation, based on the theory of Hall-Littlewood symmetric functions, of the determinant of the regular character table X RC of S n with respect to an integer r ≥ 2. This result had earlier been proved by Olsson in a longer and more indirect manner. As a consequence, we obtain a new proof of the Mathas' Conjecture on the determinant of the Cartan matrix of the Iwahori-Hecke algebra. When r is prime we determine the Smith normal form of X RC . Taking r large yields the Smith normal form of the full character table of S n . Analogous results are then given for spin characters.