An experimental program is conducted to study chloride penetration characteristics of concrete partially or fully bonded with carbon fiber reinforced polymer (CFRP) composite sheets in an aggressive service circumstance. A standard test protocol for electrical indication of concrete's ability to resist chloride ion penetration (ASTM C1202) is employed to examine the mobility of chlorides inside the concrete. The ingress of chlorides is influenced by CFRP-coverage ratios such that the current flow and resistivity are reduced with an increasing coverage ratio. The concept of near-field microwave microscopy is exploited to evaluate its potential for scanning CFRP-bonded concrete including chlorides.