Direct elemental
and isotope analyses of solid samples have attracted
considerable interest due to their potential role in preventing serious
accidents at nuclear facilities. We previously developed an analytical
method for detecting radioactive isotopes, combining diode laser absorption
spectroscopy with a supersonic plasma jet. Its basic performance,
that is, the detection limit as well as the translational temperature
upstream and downstream of the supersonic nozzle, was investigated
using stable Xe isotopes. The developed apparatus could atomize a
solid sample and reduce the translational temperature for isotope
identification. For direct isotope analysis, translational temperature
and atomization efficiency during powder feeding are remarkably important.
In the present study, a novel approach for the atomization of Sr powder
samples containing isotopes with highly radiotoxic radionuclides is
described. We found that the temperature of Sr atoms in the supersonic
plasma jet decreased to approximately 85 K, which is comparable with
the slight isotope shift of
88
Sr–
90
Sr
due to the difference in mass number. Moreover, based on the measured
atomic number density and flow velocity, the atomization efficiency
was found to be 10.4 ± 1.8%. The results of this study and further
improvements in the efficiency can lead to the development of powerful
tools for the rapid analysis of solid samples, particularly those
contaminated with highly radioactive species, without the necessity
for complex chemical separation.