Light charged particles emitted by the projectilelike fragment were measured in the direct and reverse collision of 93 Nb and 116 Sn at 25A MeV. The experimental multiplicities of hydrogen and helium particles as a function of the primary mass of the emitting fragment show evidence for a correlation with net mass transfer. The ratio of hydrogen and helium multiplicities points to a dependence of the angular momentum sharing on the net mass transfer. PACS numbers: 25.70.Lm, 25.70.Pq It is now experimentally established that binary or quasibinary dissipative processes continue to dominate the heavy-ion reaction cross section well into the intermediate energy regime [1][2][3][4][5][6][7]. In this context, a still open field of investigation concerns the degree of equilibrium attained in the internal degrees of freedom and, in particular, the partition of energy [8] and angular momentum between the two reaction partners.At low bombarding energies (#15A MeV), several experimental findings (concerning mass and charge drift, variances, excitation energies of reaction products) are rather well accounted for, in some cases also quantitatively, by models based on the stochastic exchange of single nucleons (see, e.g., [9]). At larger bombarding energies, the relevance of such a mechanism becomes somewhat uncertain, due to the decrease of interaction times, to the increasing importance of the reaction dynamics and to associated nonequilibrium effects.In the 120 Sn 1 100 Mo collision at 19.1A MeV the fission probability P fiss of the projectilelike and targetlike fragments (PLF and TLF) was measured [10] as a function of the primary mass A. For a given A, corresponding to different net mass transfers for PLF and TLF, P fiss was found to be significantly larger for the TLF (which gained mass), even at large TKEL (total kinetic energy loss). The observed effect is a clear signature of the lack of an overall equilibrium between the two partners at the end of the interaction.In the 100 Mo 1 120 Sn collision at 14.1A MeV [11] a similar behavior was found also in the binary exit channel, where the highly excited fragments deexcite mainly by light-particle emission. The observed correlation between the total number of emitted nucleons and the net mass transfer indicates a nonequilibrium excitation energy partition between the reaction products, with an excess of excitation being deposited in the fragment which gains nucleons. Similar conclusions had been drawn by other authors [12-16], but remained quite controversial. Although the existence of such correlations is compatible, by itself, with a nucleon exchange picture, the fact that they are largely independent of the degree of inelasticity [11,15] is difficult to understand within the present versions of the stochastic nucleon exchange model and deserves new investigation.Up to now no study has been performed concerning possible correlations between net mass transfer and angular momentum sharing. This Letter presents for the first time a direct evidence for a correlation betwee...