optical computers, optical switches, pulsed laser generation, optical sensors, etc. As the fundamental information carrier of NLO, nonlinear optical materials have attracted great attention since the advent of the first laser and always been the research hotspot for material and optical scientists. In the last two decades, 2D materials, representative of the main including graphene, [1-3] topological insulators (TIs), [4-6] transition metal disulfides (TMDs) [7,8] and black phosphorus (BP), [9-11] have experienced an explosive growth because of the advantages of exotic optical, electronic, chemical, and mechanical properties that much differ from their bulk counterparts. Especially, the low dimensions and distinctive nonlinear optical properties make them strongly meet the ever-increasing demand and widely used in high efficiency, compactness, broadband optoelectronic and photonic devices, broadband all-optical modulator, optical frequency conversion, pulsed laser generation, surface plasmonic, and so on. [12-19] However, there are still some disadvantages for the current 2D materials. For example, the gapless band structure and relative low light absorption of graphene limit its extensive applications; [20,21] the band gap of TMDs (1.0-2.0 eV) indicates they cannot be available in mid-infrared wavelength range; [22,23] and easy oxidation is the biggest obstacle for practical applications of BP. [24,25] Therefore, it is still an urgent demand to explore promising novel 2D nonlinear optical materials. Recently, 2D MXenes have been extensively studied due to the unique optical and electronic properties. [26,27] MXene represents a large family of 2D transition metal carbides, carbonitrides, and nitrides, with the general formula of M n+1 X n T n (n = 1-3), where M represents a transition metal (e.g., Ti, Mo, Nb), X for either C and/or N, and T is the surface functional group (e.g.,-OH,-O, and-F). [28,29] Until now, more than 30 varieties of 2D MXenes have been synthesized and theoretically and experimentally studied, [30-34] revealing the outstanding features of metallic conductivity, large electric capacity, high mechanical strength, tunable band gap, high stability, high optical transparency, and large optical nonlinearities of MXenes. [35,36] Nb 2 C is a newly discovered 2D MXene with special band structure near the Fermi level, showing the great potential applications as electrode materials Niobium carbide (Nb 2 C), a newly developed 2D MXene material, has attracted much attention due to its outstanding electronic and optical properties. In this work, few-layer 2D Nb 2 C nanosheets are synthesized by magnetron sputtering deposition method. Z-scan measurements with pump source operating at 1.0 µm are performed to study the third-order nonlinear optical response, revealing excellent light modulation capabilities of 2D Nb 2 C. The effective nonlinear absorption coefficient (β eff ≈-10 5 cm GW-1) caused by saturable absorption effect is determined to be two orders of magnitude larger than that induced by reverse sat...