This article presents the pulsed laser irradiation of heavy metals (Ta, W, Au and Pb) at 10 10 W/cm 2 power density, 1064 nm wavelength and 9 ns pulse duration. The fast irradiation produces non-equilibrium plasma, which generates ions having a high charge state (from 1 + up to 10 + ), high velocity and kinetic energy. An electrostatic ion energy analyser (IEA) permits us to detect the different ions and to record the ion energy distribution as a function of the ion charge state. The experimental distributions of the ion charge states are explained on the base of the electron-ion ionization cross-sections, according to the Lotz theoretical approach. Results indicate that at the used power densities, the process of ion recombination is negligible. By using higher power densities, the different ion charge state distributions can be explained introducing both the ionization and recombination processes occurring inside the high-temperature plasma.