The hydrogeochemical characteristics of coalbed water
play a crucial
role in assessing the production level of coalbed methane (CBM) due
to its involvement in the entire process of CBM generation, migration,
accumulation, and extraction. To investigate variations in hydrochemical
characteristics and controlling factors among different coal seams,
a representative CBM field (Baode block) within the Ordos basin in
China was chosen as a target. We have systematically collected produced
water samples from coal seams of the Permian Shanxi Formation (P1s) and Taiyuan Formation (P1t). Tests and analyses
were conducted on conventional cation and anions, trace elements,
pH value, total dissolved solids (TDS), stable isotopes of hydrogen
and oxygen in water, and inorganic carbon (δD, δ18O, and δ13CDIC). The findings indicate
that the P1s coal seam primarily contains HCO3–Na type water, while the P1t coal seam consists
of Cl–Na and HCO3–Na types of water. The
disparity in water types between P1s and P1t
can be attributed to interactions between water and rocks. The isotopic
compositions of δD, δ18O, and δ13CDIC suggest that the sampled coalbed waters originate
from atmospheric precipitation, with subsequent microbial activity.
It is suggested that TDS content along with bicarbonate concentration
can serve as effective indicators for determining high productivity
due to weaker hydraulic conditions and a more enclosed water environment
in P1t coal seams; threshold values being >1000 mg/L
for
TDS and >10 mequiv/L for bicarbonate concentration. Additionally,
microbial activity is found to be more widespread in P1t compared to P1s. Principal component analysis reveals
a significantly higher contribution of conventional ions toward TDS
content observed within the P1t coal seam compared to that
of P1s coal seam, accompanied by alterations in pH control
parameters. The water produced from the P1s coalbed is
primarily controlled by evaporite and silicate weathering/dissolution
coupled with substantial cation exchange. Conversely, the water in
the P1t coalbed is mainly influenced by silicate weathering/dissolution
as well as evaporative concentration, with a limited occurrence of
cation exchange. Moreover, there are distinct disparities in ion sources
between P1s and P1t. These research findings
provide a scientific foundation for assessing the development potential
of CBM and optimizing extraction systems within similar CBM areas.