2010
DOI: 10.1007/s12665-010-0499-1
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Geochemical processes in the saltwater–freshwater transition zone: comparing results of a sand tank experiment with field data

Abstract: Geochemical processes, occurring in a stable transition zone between saltwater and freshwater, were simulated in a 2D, multi-layer flow chamber experiment. Mixing, calcite dissolution, and oxidative degradation of organic matter were identified as the main controlling factors. The results of the chamber experiment were compared to field data and verified by thermodynamic modeling. Similarity in most ion distributions suggests the general applicability of the experimental method. Differences in the redox condit… Show more

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Cited by 19 publications
(8 citation statements)
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“…An aquifer simulator consists of a watertight container filled with a porous sediment saturated with water. Controlled groundwater flow conditions have previously been used to study the migration of a contaminant plume [41,42] and the temperature distribution in a dike [43] or to evaluate the accuracy of flowmeters measuring the horizontal groundwater velocity [8]. The AS used in this study was constructed from a metal frame with glass walls measuring 2 × 1 × 1 m (length × width × height) which was filled with sand of 0.1–0.25 mm grain sizes, a porosity of 0.41, and a hydraulic conductivity of 9 m/d.…”
Section: Methodsmentioning
confidence: 99%
“…An aquifer simulator consists of a watertight container filled with a porous sediment saturated with water. Controlled groundwater flow conditions have previously been used to study the migration of a contaminant plume [41,42] and the temperature distribution in a dike [43] or to evaluate the accuracy of flowmeters measuring the horizontal groundwater velocity [8]. The AS used in this study was constructed from a metal frame with glass walls measuring 2 × 1 × 1 m (length × width × height) which was filled with sand of 0.1–0.25 mm grain sizes, a porosity of 0.41, and a hydraulic conductivity of 9 m/d.…”
Section: Methodsmentioning
confidence: 99%
“…For example, the cation-equivalent concentration could be calculated as the sum of the product of the absolute value of the charge of a cation species z i,cat and its concentration c i,cat over all cation species N cat in the sample (Equation (1)). The total anion-equivalent concentration was determined similarly [ 21 , 22 ]. The total anion-equivalent concentration must be equal to the total cation-equivalent concentration due to the electron neutrality in the solution [ 22 , 23 ].…”
Section: Resultsmentioning
confidence: 99%
“…Mercado 1985, Barbecot et al 2000, Harbison and Cox 2002, Al-Agha and El-Nakhal 2004, Pulido-Leboeuf 2004, Sivan et al 2005, Mondal et al 2010, Panteleit et al 2011. Cation exchange between Ca 2+ in dilute groundwater and Na + in seawater is well known (Nadler et al 1980, Richter et al 1993, Petalas and Diamantis 1999, Martínez and Bocanegra 2002, Andersen et al 2005, Appelo and Postma 2005, Petalas and Lambrakis 2006).…”
Section: Introductionmentioning
confidence: 99%