“…Also, in mining environments, REE may behave as tracers of AMD contamination. In fact numerous investigations on the identification of the water-rock interactions mechanisms that govern the chemistry of acidic drainage have been done, and several publications have reported the REE geochemistry of acidic sulphate in the last two decades (Johannesson et al, 1996;Johannesson and Zhou, 1999;Verplanck et al, 1999;Marchand, 2002;Borrego et al, 2005;Gammons et al, 2005a,b;Merten et al, 2005;Olias et al, 2005;Wood et al, 2006;Ferreira da Silva et al, 2009;Pérez-Lopez et al, 2010;Delgado et al, 2012;López-González et al, 2012). These works have reported a shale-normalized pattern enriched in MREE relative to LREE and HREE.…”