The accuracy of the Global Positioning System (GPS) as an instrument for measuring the integrated water vapor content of the atmosphere has been evaluated by comparison with concurrent observations made over a 14-day period by radiosonde, microwave water vapor radiometer (WVR), and Very Long Baseline Interferometry (VLBI). The Vaisala RS-80 A-HUMICAP radiosondes required a correction to the relative humidity readings (provided by Vaisala) to account for packaging contamination; the WVR data required a correction in order to be consistent with the wet refractivity formulation of the VLBI, GPS, and radiosondes. The best agreement of zenith wet delay (ZWD) among the collocated WVR, radiosondes, VLBI, and GPS was for minimum elevations of the GPS measurements below 10Њ. After corrections were applied to the WVR and radiosonde measurements, WVR, GPS, and VLBI (with 5Њ minimum elevation angle cutoff ) agreed within ϳ6 mm of ZWD [1 mm of precipitable water vapor (PWV)] when the differences were averaged, while the radiosondes averaged ϳ6 mm of ZWD lower than the WVR. After the removal of biases between the techniques, the VLBI and GPS scales differ by less than 3%, while the WVR scale was ϳ5% higher and the radiosonde scale was ϳ5% lower. Estimates of zenith wet delay by GPS receivers equipped with Dorne-Margolin choke ring antennas were found to have a strong dependence on the minimum elevation angle of the data. Elevation angle dependent phase errors for the GPS antenna/mount combination can produce ZWD errors of greater than 30 mm over a few hour interval for typical GPS satellite coverage. The VLBI measurements of ZWD are independent of minimum elevation angle and, based on known error sources, appear to be the most accurate of the four techniques.