High-yield natural gas was discovered in well SN4 in the Ordovician Yingshan Formation in the Tarim Basin. The gas is found in unusual, silicified, carbonate reservoirs. According to the degree of silicification, the silicified reservoirs can be divided into a lower section of silicified carbonates, a middle section of limestone, and an upper section of silicified carbonates. The silicified carbonates are mainly composed of quartz and calcite, in which the reservoir space mostly occurs as vugs, inter-crystalline pores of quartz, and partial fractures. Porosity varies widely, ranging from 3 to 20.5% with strong heterogeneity. The homogenization temperatures of fluid inclusions in quartz and calcite show that the silicification temperatures were 150-190 C, with characteristics of high temperature/low salinity and low temperature/high salinity. The 87 Sr/ 86 Sr ratios of secondary calcite are 0.709336-0.709732, which are significantly higher than that of concurrent seawater, indicating that the hydrothermal fluid originated from the deep clastic strata or the basement (sialic rock). The d
13C values of the secondary calcite are similar to that of the surrounding limestone, indicating that the carbon in the secondary calcite is derived from the limestone strata, and that the secondary calcite is the product of dissolution and re-precipitation resulting from interaction between the silica-bearing hydrothermal fluids and surrounding limestones. The silicification of silica-bearing hydrothermal fluid was significantly