The Guayana Shield in Venezuela is composed of five lithotectonic provinces: 1) an Archean amphibolite-to granulite-facies gneiss terrane; 2) an Early Proterozoic greenstone-granite terrane(s); 3) an Early Proterozoic unmetamorphosed volcanoplutonic complex; 4) Early to Middle Proterozoic continental sedimentary rocks; and 5) Middle Proterozoic anorogenic rapakivi-type granite. Early Proterozoic rocks in the Amazon Federal Territory of western Venezuela are undivided and their relation to other rocks of the Venezuelan Guayana Shield is unclear. Early to Middle Proterozoic continental tholeiitic dikes, sills, and small irregular intrusive bodies and Mesozoic dikes emplaced during the opening of the Atlantic Ocean cut all of the lithotectonic provinces. Major mineral deposits of the Venezuelan Guayana Shield include gold, iron, bauxite, and diamonds. The Archean Imataca Complex, the oldest unit, consists of gneiss and granulite with minor dolomite and banded iron-formation (BIF). Large isoclinal folds, which have been refolded into relatively open folds, are common in the Imataca Complex. Metamorphic grade ranges from granulite facies in the northeast part of the belt to amphibolite facies in the southwest. Deposits of enriched BIF in the Imataca Complex contain more than 2 billion metric tons of iron ore. During the Pre-Trans-Amazonian tectonomagmatic event, between about 2,800 and 2,700 Ma, granitic rocks intruded the Imataca Complex, and injection gneisses and migmatite were developed. The Early Proterozoic greenstone belts, which formed between about 2,250 and 2,100 Ma, consist of a submarine sequence of tholeiitic mafic volcanic rocks, a sequence of tholeiitic to calc-alkaline basalt to rhyolite, and an interval of turbiditic graywacke, volcaniclastic rocks, and chemical sedimentary rocks that characterize the basal, middle, and upper parts, respectively. Layered mafic complexes also occur in the greenstone belts. The greenstone-belt rocks range in metamorphic grade from greenschist to amphibolite facies. Low-sulfide gold-quartz veins are hosted by Early Proterozoic greenstone-belt rocks cut by major shear zones. Deposits of volcanogenic manganese are mined elsewhere in the Guayana Shield; in Venezuela, a moderate potential exists for the discovery of additional deposits of manganese in the greenstone belts. Platinum-group elements (PGE) and chromium are present in anomalous values in the layered mafic complex at Piston de Uroy, Venezuela. Also, PGE are anomalous in mafic metavolcanic and metagabbroic rocks adjacent to an exhalative (Homestake-type) gold prospect in the Cerro La Pinto area. Granitic domes of the Supamo Complex intruded the greenstone-belt rocks between about 2,230 and 2,050 Ma and divided the metasedimentary and meta-igneous greenstonebelt rocks into branching synclinoria between intrusive uplifts. The Trans-Amazonian orogeny was a period of continental collision between about 2,150 and 1,960 Ma, during which the Imataca Complex and the greenstonegranite terranes were deformed and metamorphose...