We present calculations for the effect of fixed charge density (Q ss ) due to passivation on responsivity (R v ), noise (V n ) and specific detectivity (D * ) for the n-HgCdTe photoconductor (PC) overlap structure. The standard expressions of the PC overlap structure have been modified appropriately to include the effect of Q ss , present near the HgCdTe passivant interface, on the important parameters of the detector, namely resistance, responsivity, noise, detectivity and minority carrier lifetime. Our objective in this paper is to evaluate the tolerable limits of Q ss for given performance specifications. The symmetric and asymmetric PC overlap structures are studied and compared to standard non-overlap structures. Our results show that R v versus Q ss shows a peak in both symmetric and asymmetric overlap structures when Q ss is in the range of (2-3) × 10 11 cm −2 , and this optimum Q ss does not shift significantly when one moves from standard to overlap structures. Besides, this optimum Q ss is almost independent of bulk minority carrier lifetime (τ ). However, noise voltage versus Q ss shows a somewhat flat region for low Q ss , a sharply decreasing trend for high Q ss and a peak in the intermediate region. Furthermore, there is a stronger dependence on Q ss in overlap structures than in standard (non-overlap) structures. However, the parameter to be maximized, i.e. D * , shows that a value of Q ss of 2 × 10 11 cm −2 is optimum for both symmetric and asymmetric overlap structures, whereas a value of Q ss in the range of 2 × 10 11 to 1 × 10 12 cm −2 is optimum for standard structures. Additionally, we study the dependence of R v , V n and D * on detector length (a parameter increased for obtaining overlap design) and frequency for various values of Q ss in constant power mode. The predictions of the model fit reasonably well with the experimental data.