To enhance the effectiveness and accuracy of mobile station location estimation, author utilizes time of arrival measurements from three base stations and one angle of arrival information at the serving base station to locate mobile station in non-line-of-sight environments. This article makes use of linear lines of position, rather than circular lines of position, to give location estimation of the mobile station. It is much easier to solve two linear line equations rather than nonlinear circular ones. Artificial neural networks are widely used techniques in various areas due to overcoming the problem of exclusive and nonlinear relationships. The proposed algorithms employ the intersections of three linear lines of position and one angle of arrival line, based on Levenburg–Marquardt algorithm, to determine the mobile station location without requiring a priori information about the non-line-of-sight error. The simulation results show that the proposed algorithms can always provide much better location estimation than Taylor series algorithm, hybrid lines of position algorithm as well as the geometrical positioning methods for different levels of biased, unbiased, and distance-dependent non-line-of-sight errors.