2009
DOI: 10.1002/qua.22365
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Geometrical properties of nodal surfaces of many‐electron wave functions

Abstract: ABSTRACT:Hypothesis of the exclusion of equipotential surfaces for many-electron wave functions (MWF) has been enunciated. This hypothesis clarifies the physical meaning of the Pauli exclusion principle and opens the way for future progress of new quantum-chemical methods for the construction of approximate MWFs differing from the traditional Hartree-Fock approximation. The equipotential surface exclusion principle has been tested on traditional representative "test systems" of quantum mechanics: the helium at… Show more

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Cited by 7 publications
(1 citation statement)
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“…10, 11 Of course, the HPES should be comprehensively test ed and developed; probably, it should be revised or modi fied in some way. However, in any case the formulation of the HPES itself is topical and its consideration will enrich the experience of quantum chemists in search for funda mentally new non Hartree-Fock approaches.…”
mentioning
confidence: 99%
“…10, 11 Of course, the HPES should be comprehensively test ed and developed; probably, it should be revised or modi fied in some way. However, in any case the formulation of the HPES itself is topical and its consideration will enrich the experience of quantum chemists in search for funda mentally new non Hartree-Fock approaches.…”
mentioning
confidence: 99%