2020
DOI: 10.1103/physreve.102.033113
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Geometrically derived efficiency of slow immiscible displacement in porous media

Abstract: The efficiency of a displacement is the fraction of applied work over the change in free energy. This displacement efficiency is essential for linking wettability to applied work during displacement processes. We quantify the efficiency of slow immiscible displacements in porous media from pore space geometry. For this end, we introduce pore-scale definitions for thermodynamically reversible (ison) and irreverisble (rheon) processes. We argue that the efficiency of slow primary displacement is described by the… Show more

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Cited by 11 publications
(7 citation statements)
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References 39 publications
(67 reference statements)
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“…The dynamics of slow displacement in porous media has been observed to occur in an intermittent manner by so called Haines jumps [59,[62][63][64][65][66][67][68][69][70][71][72]. The invasion percolation model [55][56][57] describes well the structure of slow displacement in porous media [22], but it does not describe the dynamics realistically because the invasion is limited to one pore at a time.…”
Section: Introductionmentioning
confidence: 99%
“…The dynamics of slow displacement in porous media has been observed to occur in an intermittent manner by so called Haines jumps [59,[62][63][64][65][66][67][68][69][70][71][72]. The invasion percolation model [55][56][57] describes well the structure of slow displacement in porous media [22], but it does not describe the dynamics realistically because the invasion is limited to one pore at a time.…”
Section: Introductionmentioning
confidence: 99%
“…(with contact angle θ ≈ 0 • for a water-wet system and radius r = d/2) for a water-wet system as p c = 0.017 bar for pore bodies and p c = 0.04 bar for pore throats, which are also typical values for the pressure fluctuations in the steady-state experiment in Figures 2-5 (the maximum fluctuations can be a factor 3-4 larger but for most f w the range is very similar) (Berg C. F. et al, 2020). This suggests that the pressure fluctuations are likely caused by events on the capillary energy scale, which are typically pore scale events.…”
Section: Energy Scale Of Fluctuationsmentioning
confidence: 55%
“…Pore scale experiments (DiCarlo et al, 2003;Moebius and Or, 2012;Berg et al, 2013Berg et al, , 2014Armstrong et al, 2014a;Reynolds et al, 2017;Lin Q. et al, 2018;Lin et al, 2019a) and numerical simulations (Lenormand et al, 1983;Raeini et al, 2014;Armstrong et al, 2015;Guédon et al, 2017;Alpak et al, 2019;Berg C. F. et al, 2020;Winkler et al, 2020) also exhibit fluctuations in pressure and saturation (Ramstad and Hansen, 2006;Pak et al, 2015), which are caused by pore scale displacement events, such as Haines jumps and coalescence (Rücker et al, 2015b), where the non-wetting phase replaces the wetting phase and snap-off and pistonlike displacement (Lenormand et al, 1983;Dixit et al, 1998), where the wetting phase replaces the non-wetting phase. These events lead to interruption and rearrangement of the connected pathways the respective phases flow through (Tuller and Or, 2001) and are described by a rigorous theoretical framework of pore-scale thermodynamics (Morrow, 1970).…”
Section: Introductionmentioning
confidence: 99%
“…An analytical expression for u w in unsaturated hydrophobic soil can be derived by quantifying the change of free surface energy due to external work. The pressure of non-wetting water phase (P w ) during infiltration results in an increase in the soil water content (Δθ w ) and thereby changes the interfacial energies (E IE ) between soil-air-water phases (Berg et al, 2020), which can be expressed as:…”
Section: Effective Stress Of Unsaturated Soil With Varied Wettabilitymentioning
confidence: 99%