Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O12

Yamada, Ikuya; Tsuchida, Kazuki; Ohgushi, Kenya; Hayashi, Naoaki; Kim, Jung-Eun; Tsuji, Naruki; Takahashi, Ryōji; Matsushita, Masafumi; Nishiyama, Norimasa; Inoue, Toru; Irifune, Tetsuo; Kato, Kenichi; Takata, Masaki; Takano, Mikio

doi:10.1002/anie.201102228

Cited by 137 publications

(118 citation statements)

References 21 publications

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“…This oxide has NTE of α = −82 ppm K −1 at T = 320-380 K (figure 7). A similar NTE was observed for LaCu 3 Fe 4 O 12 [32][33][34], which results from the charge transfer from Fe to Cu upon heating.…”

Section: Atomic Radius Contractionsupporting

confidence: 72%

“…This was a theoretical attempt to explain magnetovolume effects from the viewpoint of atomic radius contraction. NTE arising from atomic radius contraction has been discovered recently in perovskite oxides [32][33][34][35] [35] undergoes a first-order phase transition from the larger-volume low-T phase to the smaller-volume high-T phase. The volume change reaches 2.9%.…”

Section: Atomic Radius Contractionmentioning

confidence: 99%

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Negative thermal expansion materials: technological key for control of thermal expansion

Takenaka

2012

Science and Technology of Advanced Materials

489

311

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Most materials expand upon heating. However, although rare, some materials contract upon heating. Such negative thermal expansion (NTE) materials have enormous industrial merit because they can control the thermal expansion of materials. Recent progress in materials research enables us to obtain materials exhibiting negative coefficients of linear thermal expansion over −30 ppm K −1 . Such giant NTE is opening a new phase of control of thermal expansion in composites. Specifically examining practical aspects, this review briefly summarizes materials and mechanisms of NTE as well as composites containing NTE materials, based mainly on activities of the last decade.

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Section: Atomic Radius Contractionsupporting

confidence: 72%

Section: Atomic Radius Contractionmentioning

confidence: 99%

Negative thermal expansion materials: technological key for control of thermal expansion

Takenaka

2012

Science and Technology of Advanced Materials

489

311

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“…Polycrystalline ACu 3 Fe 4 O 12 (A ¼ Ca, Sr, Y and Eu) samples were prepared under high pressure and high temperature conditions of 15e20 GPa, 1000e1200 C [9,10,12]. Note that EuCu 3 Fe 4 O 12 (ECFO) compound displays an intersite charge transfer below 250 K as LCFO does below 393 K (unpublished).…”

Section: Methodsmentioning

confidence: 99%

“…CaCu 3 Fe 4 O 12 (CCFO) and YCu 3-Fe 4 O 12 (YCFO) show charge disproportionation (2Fe 4þ / Fe 3þ þ Fe 5þ ) and a ferrimagnetism resulting from antiferromagnetic interactions between Cu and Fe sublattices, below 210 K and 250 K respectively [9,10]. In contrast, LaCu 3 Fe 4 O 12 (LCFO) and SrCu 3 Fe 4 O 12 (SCFO) demonstrate an intersite charge transfer between Cu and Fe ions (3Cu 2þ þ 4Fe 3.75þ / 3Cu 3þ þ 4Fe 3þ for LCFO and Cu 2þ þ Fe 4þ / Cu 3þ þ Fe 3þ for SCFO) below 393 K and 270 K, respectively [11,12].…”

Section: Introductionmentioning

confidence: 94%

“…an increase in the distance thus produces a shift to lower wavenumber (redshift), which is not the case for the compounds studied here. Evolution of Raman mode wavenumbers suggests then a modification in binding energy and can be related to the results obtained by bond valence sums (BVS) calculations[9,10,12,16]. These have shown that SCFO and ECFO present underbonding of FeeO bond and overbonding of AeO bond, while CCFO and YCFO exhibit overbonding FeeO bond and underbonding AeO bond.…”

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confidence: 95%

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Raman study of ACu3Fe4O12 (A = Ca, Sr, Y and Eu)

Zaghrioui

Yamada

Shiro

et al. 2014

Solid State Sciences

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High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation

Inaguma

2017

Handbook of Solid State Chemistry

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A huge number of compounds with chemical formula ABX 3 adopt the perovskite (Pv)‐type structure or its distorted derivatives. Studies on Pv‐type and related compounds synthesized under high pressures and high temperatures or stable under high pressure have been developed by large contributions of earth science as well as materials science and engineering. In the field of solid‐state chemistry, the stabilization of Pv‐phase by high pressure, the phase relation under various pressure‐temperature conditions, and the structure and properties of obtained metastable Pv phases have been elucidated. This chapter reviews syntheses of high‐pressure Pv in terms of synthetic methods, phase stability, structure, and chemical bonding. Synthetic methods of Pvs aided by pressure, from relative low gas pressure of ∼1 MPa to hydrostatic pressure in solid medium on the order of 10 GPa and the examples.

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Giant Negative Thermal Expansion in the Iron Perovskite SrCu₃Fe₄O₁₂

Cited by 137 publications

References 21 publications

Negative thermal expansion materials: technological key for control of thermal expansion

Negative thermal expansion materials: technological key for control of thermal expansion

Raman study of ACu3Fe4O12 (A = Ca, Sr, Y and Eu)

High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation

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