1996
DOI: 10.1016/s0921-4534(96)00480-7
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Giant pressure effect in oxygen deficient YBa2Cu3Ox

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Cited by 63 publications
(44 citation statements)
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“…3, yielding E A (1 bar) ≃ 0.84 eV and 0.90 eV, respectively. These values are quite comparable to each other and to activation energies determined from relaxation studies on Y-123 (0.97 eV) [14,16], Tl-2201 (0.72 eV) [23] and Tl-1212 (0.86 eV) [17], as well as to oxygen tracer diffusion studies on Y-123 and other oxide superconductors [41]. This fact, and the known sensitivity of the relaxation behavior to the oxygen content [13,16], make it likely that the above relaxation effects originate in the oxygen sublattice.…”
Section: B Relaxation Behavior At Ambient Pressuresupporting
confidence: 80%
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“…3, yielding E A (1 bar) ≃ 0.84 eV and 0.90 eV, respectively. These values are quite comparable to each other and to activation energies determined from relaxation studies on Y-123 (0.97 eV) [14,16], Tl-2201 (0.72 eV) [23] and Tl-1212 (0.86 eV) [17], as well as to oxygen tracer diffusion studies on Y-123 and other oxide superconductors [41]. This fact, and the known sensitivity of the relaxation behavior to the oxygen content [13,16], make it likely that the above relaxation effects originate in the oxygen sublattice.…”
Section: B Relaxation Behavior At Ambient Pressuresupporting
confidence: 80%
“…These values are quite comparable to each other and to activation energies determined from relaxation studies on Y-123 (0.97 eV) [14,16], Tl-2201 (0.72 eV) [23] and Tl-1212 (0.86 eV) [17], as well as to oxygen tracer diffusion studies on Y-123 and other oxide superconductors [41]. This fact, and the known sensitivity of the relaxation behavior to the oxygen content [13,16], make it likely that the above relaxation effects originate in the oxygen sublattice. To our knowledge, no attempt has yet been made to compute the energy barrier for oxygen diffusion in Hg-1201; in a recent model calculation Islam and Winch [42] have estimated E A (1 bar) ≈ 0.68 eV for the migration of interstitial O(4) oxygen in the three-layer compound Hg-1223, a value roughly comparable to our present result for Hg-1201.…”
Section: B Relaxation Behavior At Ambient Pressuresupporting
confidence: 80%
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“…This enhancement was attributed to the pressure-induced ordering of the chain oxygen in analogy to the results of the annealing experiments of Veal et al [83]. The pressure-induced redistribution of oxygen was investigated in more detail with respect to the characteristic time relaxation of T c at different temperatures [91,92]. Changing pressure abruptly at room temperature and measuring T c at different times after storing the pressurized sample at 298 K a typical relaxation behavior as shown in Fig.…”
Section: Pressure-induced Redistribution Of Mobile Oxygen In Htsmentioning
confidence: 59%
“…With increasing δ YBa 2 Cu 3 O 7-δ becomes under-doped and more oxygen vacancies are created in the CuO chains. A giant pressure coefficient dT c /dp of up to 30 K/GPa was reported for very under-doped YBa 2 Cu 3 O 7-δ [91] (see Fig. 12) when pressure was imposed at room temperature.…”
Section: Pressure-induced Redistribution Of Mobile Oxygen In Htsmentioning
confidence: 91%