“…It is observed that, there are two main frequency bands, namely, high frequency band n 1 (575-580 cm À 1 ) and low frequency band n 2 (around 400 cm À 1 ). These two observed bands (n 1 and n 2 ) correspond to the intrinsic vibrations of tetra- from 420 to 450 cm À 1 are due to the presence of different metal ions at the octahedral site [14][15][16]. Fig.…”