Early Pliocene to Pleistocene volcaniclastic sediments recovered during Ocean Drilling Program Leg 135 from Sites 834 to 839 in the Lau Basin show a wide range of chemical and mineralogical compositions extending the spectrum previously known from the Lau Basin, Lau Ridge and Tofua Arc. The following major types of volcaniclastics have been distinguished: (1) primary fallout ashes originating from eruptions on land, (2) epiclastic deposits that resulted from subaerial and submarine eruptions, (3) subaqueous fallout and pyroclastic flow deposits resulting from explosive submarine eruptions, and (4) hyaloclastites resulting from mechanical fragmentation and spalling of chilled margins of submarine pillow tubes and sheet-lava flows.Vitric shards are mostly basaltic andesitic to rhyolitic and broadly follow two major trends in terms of K 2 O enrichment: a low-K series (LKS) with about 1 wt% K 2 O at 70 wt% SiO 2 , and a very low-K series (VLKS) with only about 0.5 wt% K 2 O at 70 wt% SiO 2 .Sites 834 and 835 on "old" backarc basin crust, >4.2 and 3.4 m.y. old, comprise LKS rhyolites >3.3 m.y. old. Calc-alkaline basaltic turbidites originating from the Lau Ridge flowed in at 3.3 Ma. In the period from 3.3 to 2.4 Ma basaltic andesitic to rhyolitic, fine-grained LKS and VLKS volcaniclastics were deposited by turbidity currents and subaerial fallout. Three thin, discrete fallout layers (2.4-3.2 m.y. old) with high-K calc-alkaline compositions probably erupted in New Zealand.Volcaniclastics from Site 836, all <0.6 m.y. old, make up 24% of the sediments and comprise local basaltic andesitic to andesitic hyaloclastites with low Ba/Zr ratios of 0.9 to 1.4 and polymict andesitic sediments with Ba/Zr ratios of up to 5.5, containing clasts altered to lower greenschist facies.In Sites 837-839, drilled on young crust (1.8-2.1 m.y. old), volcaniclastics make up 45%-64% of the total sediment. Glass compositions are often bimodal with a mafic and a rhyolitic population. Large-volume rhyolitic, silt-to lapilli-sized volcaniclastics are interpreted as pyroclastic flows from explosive eruptions on a seamount 25-50 km away from the sites. Ba/Zr ratios are 2 to 4, partially overlapping with some Lau Basin basement lavas that show an "arc" signature, and they can reach values >5 in thin volcaniclastic layers <0.6 m.y. old.