Glass–Zirconia Composites as Seals for Solid Oxide Cells: Preparation, Properties, and Stability over Repeated Thermal Cycles

Abstract

This study focuses on the preparation and characterization of composite gaskets designed for the sealing of the solid oxide cell stacks operating below 700 °C. The seals were fabricated with the addition of various amounts (10–90 wt.%) of 3 mol.% yttria partially stabilized zirconia to a BaO-Al2O3-CaO-SiO2 glass matrix. The sample gaskets in the form of thin frames were shaped by tape casting. The quality of the junctions between the composites and Crofer 22APU steel commonly used as an SOC interconnect was evaluated after thermal treatment of heating to 710 °C, then cooling to the working temperature of around 620 °C and then leaving them for 10h in an air atmosphere, before cooling to room temperature. The samples were also studied after 3, 5, and 10 thermal cycles to determine the changes in microstructure and to evaluate the porosity and possible crystallization of the glass phase. The compression of the seals was calculated on the basis of differences in thickness before and after thermal treatment. The influence of zirconia additions on the mechanical properties of the seals was studied. The experimental results confirmed that glass–ceramic composites are promising materials for gaskets in SOC stacks. The most beneficial properties were obtained for a composite containing 40 wt.% of YSZ.

Barium Silicate Glasses and Glass–Ceramic Seals for YSZ-Based Electrochemical Devices

“…Barium silicate glasses are the most widespread glass and glass-ceramic sealants due to their good stability at high temperatures, high mechanical strength, appropriate coefficient of thermal expansion, and low electrical conductivity [17][18][19]. The properties of glass sealants can be controlled by changing the glass composition [20][21][22] and the introduction of filles into the glass matrix to obtain composites [19,23,24]. Several scientific groups studying barium-containing and barium-free glass sealants and led by the following scientists can be mentioned: K. Singh and G. Kaur [20,25,26], F. Smeacetto and A.G. Sabato [27][28][29], X. Wang and Y. Dong [19,30,31], and A. Kuzmin and N. Saetova [32][33][34][35].…”