There has been very little published research on glowing connections, especially their mechanisms and properties. In this study, oxide conductivity, surface x-ray maps, temperature measurements, and electrical waveforms were used to identify the structure and composition of glowing connections. It is shown that a glowing connection consists of a glowing molten liquid filament, which produced the orange glow that meanders on the surface of a solid copper oxide bridge that forms between two wires.Temperature and video measurements indicate that the glowing filament is in a liquid state.With the addition of oxide bridge resistivity measurements, the saw-tooth voltage pattern, typically seen in currents below 5Arms, has been explained. Also, when the glowing connection was slowly cooled, an impression of the glowing filament remained on the solid oxide. Subsequent SEM and x-ray mappings of this glow track revealed a track rich in copper, oxygen, and sulfur. This glow track explains the occasional low resistance path across the wires that can occur when the solid oxide bridge remains intact after cooling. Measurements in vacuum showed that oxygen was necessary to sustain the glowing filament even if there was a preexisting CuO oxide bridge present. Physical parameters affecting glow characteristics will be discussed; especially the semi-conducting nature of the copper oxide, and a model of the glowing contact, based on this data, that show some of the significant factors controlling the glow.