Glycine in a basket: protonated complexes of 1,1,n,n-tetramethyl[n](2,11)teropyrenophane (n = 7, 8, 9) with glycine in the gas-phase

Chen, Yanyang; Ghasemabadi, Parisa Ghods; Bodwell, Graham J.; Demireva, Maria; Fridgen, Travis D.

doi:10.1039/d3cp00781b

Phys. Chem. Chem. Phys.

2023

DOI: 10.1039/d3cp00781b

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Glycine in a basket: protonated complexes of 1,1,n,n-tetramethyl[n](2,11)teropyrenophane (n = 7, 8, 9) with glycine in the gas-phase

Yanyang Chen

Parisa Ghods Ghasemabadi

Graham J. Bodwell

et al.

Abstract: Protonated complexes composed of a basket-like host molecule 1,1,n,n-tetramethyl[n](2,11)teropyrenophanes (TMnTP) (n=7, 8, 9) and glycine as a guest were studied in the gas phase by experimental and computational methods. Blackbody...

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Cited by 3 publications

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Long‐range Through‐space Charge Transfer in a pH‐responsive Mixed Cyclophane of Pyridine and Teropyrene

Ghasemabadi,

Tabasi,

Salari

et al. 2023

Chemistry A European J

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A large, strained (SE = 44.2 kcal/mol) and conformationally flexible mixed cyclophane of pyridine and teropyrene was synthesized using two intramolecular Wurtz coupling reactions and an unprecedented Scholl reaction between the unreactive 2 positions of the pyrene systems in a triply bridged pyrenophane. Protonation of the pyridine unit results in a greatly enhanced preference for nesting in the cavity of the highly bent teropyrene system (θcalc = 162.6°) and emergence of a charge transfer absorption band (λmax = 592 nm) due to a long range (5.0‐5.5 Å), through‐space intramolecular transition between the teropyrene and pyridinium units, which does not exist in the neutral cyclophane.

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Long‐range Through‐space Charge Transfer in a pH‐responsive Mixed Cyclophane of Pyridine and Teropyrene

Ghasemabadi,

Tabasi,

Salari

et al. 2023

Chemistry A European J

Self Cite

View full text Add to dashboard Cite

show abstract

How hot are weakly-bound cluster ions in a blackbody field? Insights from master equation modeling

Demireva

2024

International Journal of Mass Spectrometry

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Structures and unimolecular chemistry of alkali metal cation complexes with glutathione in the gas phase

Sharifi,

Loire,

Martens

et al. 2024

International Journal of Mass Spectrometry

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Glycine in a basket: protonated complexes of 1,1,n,n-tetramethyl[n](2,11)teropyrenophane (n = 7, 8, 9) with glycine in the gas-phase

Abstract: Protonated complexes composed of a basket-like host molecule 1,1,n,n-tetramethyl[n](2,11)teropyrenophanes (TMnTP) (n=7, 8, 9) and glycine as a guest were studied in the gas phase by experimental and computational methods. Blackbody...

Cited by 3 publications

References 80 publications

Long‐range Through‐space Charge Transfer in a pH‐responsive Mixed Cyclophane of Pyridine and Teropyrene

Long‐range Through‐space Charge Transfer in a pH‐responsive Mixed Cyclophane of Pyridine and Teropyrene

How hot are weakly-bound cluster ions in a blackbody field? Insights from master equation modeling

Structures and unimolecular chemistry of alkali metal cation complexes with glutathione in the gas phase

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