A series of 2,7-disubstituted 3-methylimidazo[1,2-c][1,3]oxazin-5-one were synthesized in good yields via Ag2CO3/TFA-mediated an intramolecular annulation of N-Boc-2-alkynyl-4-bromo(alkynyl)-5-methylimidazoles. This methodology was carried out in the presence of a catalytic amount of...