2024
DOI: 10.1021/acs.orglett.4c01872
|View full text |Cite
|
Sign up to set email alerts
|

Gold-Catalyzed Homo/Heterodimerization of Terminal Alkynes Facilitated by Metal–Ligand Cooperation

Xuan Wu,
Liming Zhang

Abstract: Gold-catalyzed dimerization of terminal alkynes is achieved under mild reaction conditions and in excellent yields. In addition to homodimerizations, heterodimerizations between TBS acetylene and a range of terminal alkynes were realized using the syringe pump technique. The reaction tolerates various functional groups. The rate acceleration experienced in the reactions is enabled by metal−ligand cooperation. A binaphthyl-2-ylphosphine ligand featuring a 3′-diisopropylphosphoryl group plays a pivotal role in f… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2024
2024
2025
2025

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
references
References 21 publications
0
0
0
Order By: Relevance