2014
DOI: 10.1016/j.jpowsour.2013.06.156
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Gold coating for a high performance Li4Ti5O12 nanorod aggregates anode in lithium-ion batteries

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Cited by 130 publications
(70 citation statements)
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“…This kind of battery draws much attention in the past decades with increasing energy demand and environmental problems caused by fossil fuels consuming. The development of LIBs in the past is based on the development of electrode materials, such as spinel LiMn 2 O 4 and their derivation materials [6][7][8], olivine phosphate [9][10][11], silicon based materials [12][13][14], Li 4 Ti 5 O 12 [15][16][17][18][19][20][21][22], besides the commonly used LiCoO 2 and graphite. Among these electrode materials, Li 4 Ti 5 O 12 has been demonstrated as one of the most promising anode materials for LIBs since it exhibits ultra-long lifetime with zero structural change during the lithium insertion/extraction process and a relatively higher operating voltage (1.55 V vs. Li/Li + ) to ensure better safety of LIBs by avoiding the formation of lithium dendrites than the graphite electrode.…”
Section: Introductionmentioning
confidence: 99%
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“…This kind of battery draws much attention in the past decades with increasing energy demand and environmental problems caused by fossil fuels consuming. The development of LIBs in the past is based on the development of electrode materials, such as spinel LiMn 2 O 4 and their derivation materials [6][7][8], olivine phosphate [9][10][11], silicon based materials [12][13][14], Li 4 Ti 5 O 12 [15][16][17][18][19][20][21][22], besides the commonly used LiCoO 2 and graphite. Among these electrode materials, Li 4 Ti 5 O 12 has been demonstrated as one of the most promising anode materials for LIBs since it exhibits ultra-long lifetime with zero structural change during the lithium insertion/extraction process and a relatively higher operating voltage (1.55 V vs. Li/Li + ) to ensure better safety of LIBs by avoiding the formation of lithium dendrites than the graphite electrode.…”
Section: Introductionmentioning
confidence: 99%
“…To overcome the significant drawbacks of Li 4 Ti 5 O 12 , several approaches have been developed to improve the conductivity or electron transfer of Li 4 Ti 5 O 12 . One route is to synthesis nanostructure Li 4 Ti 5 O 12 materials including nanoparticles [16][17][18], nanorods [19], nanoplates [20] and so on. The nanostructures can reduce diffusion paths of both electron and lithium ions.…”
Section: Introductionmentioning
confidence: 99%
“…In particular, by using flexible current collectors such as carbon nanotubes and fibers, flexible LTO composite electrodes have been obtained [71,86]. In addition, combining LTO with conducting metallic nanoparticles can also improve the rate performance of LTO electrodes [87][88][89][90][91][92][93][94]. These improvements are noteworthy but still insufficient for power and flexibilityoriented applications.…”
Section: Impedance Spectroscopymentioning
confidence: 99%
“…10 À9 to 10 À13 cm 2 s À1 ) of LTO degrades its electrochemical performance and hinders practical application for high current applications before any materials modifications. So far, the conductivity and rate performance of LTO have been achieved by using foreign atoms doping [4,[6][7][8][9][10][11][12][13][14], nanostructures [15][16][17] and electronically conductive coatings [18][19][20][21][22][23][24][25]. Among these methods, preparation of LTO/carbon composites by a facile route is practicable and economical for large-scale industrialization [21,26].…”
Section: Introductionmentioning
confidence: 99%