Gold‐functionalized stainless‐steel wire and tube for fiber‐in‐tube solid‐phase microextraction coupled to high‐performance liquid chromatography for the determination of polycyclic aromatic hydrocarbons

Abstract

A fiber-in-tube solid-phase microextraction device based on a gold-functionalized stainless-steel wire and tube was developed and characterized by scanning electron microscopy and energy dispersive X-ray spectroscopy. In combination with high-performance liquid chromatography, it was evaluated using six polycyclic aromatic hydrocarbons as model analytes. Important parameters including sampling rate, sample volume, organic solvent content and desorption time were investigated. Under optimized conditions, an online analysis method was established. The linearity was in the range of 0.15-50 μg/L with correlation coefficients ranging from 0.9989 to 0.9999, and limits of detection ranged from 0.05 to 0.1 μg/L. The method was applied to determine model analytes in mosquito-repellent incense ash and river water samples, with recoveries in the range of 85-120%.

Diamond nanoparticles coating for in‐tube solid‐phase microextraction to detect polycyclic aromatic hydrocarbons

“…Compared with these methods, SPME has higher sensitivity, less time and solvent consumption. As a specific form of SPME, in‐tube SPME has been widely used in various fields, like as pharmaceutical, biochemistry, food and environmental analysis and so on , that can get online quick extraction and sensitive analysis via combining with HPLC . The extraction performance depends on the extraction coatings, and the development of efficient coatings is the most important for in‐tube SPME.…”

“…Compared with these methods, SPME has higher sensitivity, less time and solvent consumption. As a specific form of SPME, in-tube SPME [8,9] has been widely Article Related Abbreviations: Ace, acenaphthene; Acy, acenaphthylene; Ant, anthracene; DAD, diode array detector; FlA, fluoranthene; FLD, fluorescence detection; Flu, fluorene; Nap, naphthalene; PAHs, polycyclic aromatic hydrocarbons; Phe, phenanthrene; Pyr, pyrene; r, correlation coefficient used in various fields, like as pharmaceutical, biochemistry, food and environmental analysis and so on [10], that can get online quick extraction and sensitive analysis via combining with HPLC [11]. The extraction performance depends on the extraction coatings, and the development of efficient coatings is the most important for in-tube SPME.…”

Poly(ionic liquids)‐coated stainless‐steel wires packed into a polyether ether ketone tube for in‐tube solid‐phase microextraction

“…Commercial GC columns were early used as in‐tube SPME device . Then fused‐silica capillary , metal tube , and polyether ether ketone (PEEK) tube were modified with coating materials for in‐tube SPME. PEEK tube is suitable for in‐tube SPME because of high‐pressure resistance, good flexibility, and easy cutting.…”

“…Commercial GC columns were early used as in-tube SPME device [7]. Then fused-silica capillary [8,9], metal tube [10][11][12], and polyether Abbreviations: Ace, acenaphthylene; Ana, acenaphthene; Ant, anthracene; BaP, benzo(a)pyrene; BpA, 1,2-benzophenanthrene; EDS, energy-dispersive X-ray spectrometer; FlA, fluoranthene; Flu, fluorine; Nap, naphthalene; PAH, polycyclic aromatic hydrocarbon; Phe, phenanthrene; Pyr, pyrene; SDBS, sodium dodecyl benzene sulfonate Conflict of interest: The authors have declared no conflict of interest. ether ketone (PEEK) tube [13,14] were modified with coating materials for in-tube SPME.…”

Rapid in situ growth of oriented titanium-nickel oxide composite nanotubes arrays coated on a nitinol wire as a solid-phase microextraction fiber coupled to HPLC-UV

“…In particular great efforts were made to the metal‐based fibers such as stainless steel , zinc , gold , silver , titanium , and nitinol wires. Moreover the hybridization of NMs with metallic substrates is very interesting in SPME because it combines the strong extraction capability of NMs with unusual mechanical strength of metallic substrates .…”