2024
DOI: 10.1021/jacs.4c12063
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Gold/HNTf2-Cocatalyzed Asymmetric Annulation of Diazo-Alkynes: Divergent Construction of Atropisomeric Biaryls and Arylquinones

Yi-Bo Wang,
Wei Liu,
Ting Li
et al.

Abstract: Due to the inherent challenges posed by the linear coordination of gold(I) complexes, asymmetric gold-catalyzed processes remain challenging, particularly in the atroposelective synthesis of axially chiral skeletons. Except for extremely few examples of intramolecular annulations, the construction of axial chirality via asymmetric goldcatalyzed intermolecular alkyne transformation is still undeveloped. Herein, a gold/HNTf 2 -cocatalyzed asymmetric diazo-alkyne annulation is developed, allowing the atroposelect… Show more

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