We propose a comprehensive theory to analyze the Goos–Hänchen (GH) shift for an arbitrarily polarized Airyprime beam reflected at the air–dielectric interface. We derive general expressions for the spatial and angular GH shifts and establish a close relationship between the GH shift of the Airyprime beam and the GH shift of the Airy beam. We also predict the novel optical effects of a significantly enhanced spatial GH shift and an almost disappeared angular GH shift when the horizontally polarized Airyprime beam is reflected near Brewster’s angle.