In this paper we show that if the class f of R-modules is closed under well ordered direct limits, then the class f is preenveloping in the category of Rmodules if and only if the class dwf is preenveloping in the category of Rcomplexes, where dwf denotes the class of all complexes with all components in f. As an immediate consequence, we get that over commutative and Noetherian rings with dualizing complexes every complex admits a Gorenstein flat preenvelope. MATHEMATICS SUBJECT CLASSIFICATION (2010). 16E05, 18G35. KEYWORDS. (pre)envelopes, Gorenstein injective modules (complexes), FP-injective modules, Gorenstein flat modules (complexes).