Gradual solid-state redox-isomerism in the lanthanide series
Daria A. Lukina,
Alexandra A. Skatova,
Roman V. Rumyantcev
et al.
Abstract:The dithiocarbamate derivative [(ArBIG-bian)Yb{SC(S)NMe2}(dme)] (2) exhibits a unique gradual solid-state redox-isomerism that involves a temperature-induced reversible electron transfer between the metal and the ligand.
Coordination networks based on lanthanide ions entangle collective magnetic phenomena, otherwise only observed in inorganic 4f materials, and the tunable spatial and electronic structure engineering intrinsic to coordination chemistry. We...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.