2024
DOI: 10.1039/d4dt00484a
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Gradual solid-state redox-isomerism in the lanthanide series

Daria A. Lukina,
Alexandra A. Skatova,
Roman V. Rumyantcev
et al.

Abstract: The dithiocarbamate derivative [(ArBIG-bian)Yb{SC(S)NMe2}(dme)] (2) exhibits a unique gradual solid-state redox-isomerism that involves a temperature-induced reversible electron transfer between the metal and the ligand.

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