2013
DOI: 10.1016/j.eurpolymj.2012.09.017
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Grafting onto a renewable unsaturated polyester via thiol–ene chemistry and cross-metathesis

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Cited by 39 publications
(30 citation statements)
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“…While CM has also been used for end-group functionalisation 26,27 and cross-linking for self-healing polymers, 28,29 the development of CM to directly functionalise polymer backbones is of growing importance. 25,[30][31][32][33][34][35][36] To the best of our knowledge Coates et al were the first to propose CM functionalisation of alkene containing polyolefins as a general strategy for developing functional polymer architectures in 2004. 30 The authors synthesised a variety of copolymers, exemplified by polymer 16 (Scheme 7).…”
Section: Post-polymerisation Cross Metathesis For Polymer Functionalimentioning
confidence: 99%
“…While CM has also been used for end-group functionalisation 26,27 and cross-linking for self-healing polymers, 28,29 the development of CM to directly functionalise polymer backbones is of growing importance. 25,[30][31][32][33][34][35][36] To the best of our knowledge Coates et al were the first to propose CM functionalisation of alkene containing polyolefins as a general strategy for developing functional polymer architectures in 2004. 30 The authors synthesised a variety of copolymers, exemplified by polymer 16 (Scheme 7).…”
Section: Post-polymerisation Cross Metathesis For Polymer Functionalimentioning
confidence: 99%
“…In order to synthesize a monomer with a terminal double bond, malonization of methyl 10undecenoate was carried out. 80 The resulting malonate was then subjected to polycondensation with 1,6-hexanediol to afford an unsaturated aliphatic polyester. Thiol derivatives were reacted with the polyester in quantitative yields.…”
Section: Scheme 15mentioning
confidence: 99%
“…For polymer modification targeting discrete and soluble products though, such crosslinking is not only undesired, but even disastrous. This M a n u s c r i p t 29 problem was addressed by Meier's group in the side-chain modification of polyesters and poly(2-oxazoline)s with terminal double bonds in the side chains via CM [184,185]. In their work, polymers with terminally unsaturated side-chains (type I olefins) were reacted with type II or III CM partners including a variety of acrylates, using Hoveyda-Grubbs 2 nd generation catalyst.…”
Section: Olefin Cross-metathesismentioning
confidence: 99%