Grafting onto carbon black having few functional groups 7. Anionic graft polymerization from porous carbon black initiated by poly(potassium acrylate) retained in the pores.

Tsubokawa, Norio; Tsuchida, Hideyo; Kobayashi, Kiyotaka

doi:10.2324/gomu.66.124

Cited by 4 publications

(3 citation statements)

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“…Anionic, , cationic, − and radical − graft polymerizations onto carbon black have been investigated. Radical polymerizations can tolerate many functional groups and can be performed under mild conditions.…”

mentioning

confidence: 99%

Grafting Poly(n-butyl acrylate) from a Functionalized Carbon Black Surface by Atom Transfer Radical Polymerization

Liu¹,

Jia²,

Kowalewski³

et al. 2003

Langmuir

120

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The functionalization of a carbon black surface with atom transfer radical polymerization (ATRP) initiating sites and subsequent ATRP of n-butyl acrylate (n-BA) from the surface of carbon black is reported. The polymerizations were carried out using CuBr/N,N,N′,N′,N′′-pentamethyldiethylenetriamine and CuBr2/ 4,4′-di(5-nonyl)-2,2′-bipyridine as the catalytic system at 70 °C. A significant amount of polymers was attached to the carbon black as determined by thermogravimetric analysis and light scattering experiments. The molecular weights of the polymers grafted on carbon black were determined by detachment experiments and measured by gel permeation chromatography. The presence of dense poly(n-BA) brushes around carbon black aggregates was confirmed by atomic force microscopy. The resulting poly(n-BA)-bound carbon blacks formed stable dispersions in organic solvents for poly(n-BA).

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confidence: 99%

Grafting Poly(n-butyl acrylate) from a Functionalized Carbon Black Surface by Atom Transfer Radical Polymerization

Liu¹,

Jia²,

Kowalewski³

et al. 2003

Langmuir

120

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“…To improve its dispersion ability in polymeric systems or solvents, grafting polymer onto the carbon black surface is known to be one of the effective methods. Anionic,7, 8 cationic,9–11 radical,12–15 and atom‐transfer radical polymerization16, 17 grafting polymers onto carbon black have been investigated extensively.…”

Section: Introductionmentioning

confidence: 99%

Modification of carbon black through grafting multihydroxyl hyperbranched polyether onto its surface

Yang

Wang

Xiang

et al. 2006

J of Applied Polymer Sci

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ABSTRACT:The hydroxy methyl groups were introduced onto the pristine carbon black surface through the reaction between unsaturated hydrogen atoms of the polycondensed aromatic rings of carbon black and formaldehyde in alkali condition. Using the resultant hydroxy methyl groups on the carbon black surface as the growth point, multihydroxyl hyperbranched polyether was grafted onto the carbon black surface by cationic ring-opening polymerization of 3-ethyl-3-(hydroxymethyl)-oxetane in the presence of BF 3 ⅐OEt 2 to improve its dispersion ability in solvents. It was found that the modified carbon black could be dispersed in polar solvents, such as ethanol, chloroform, and DMF.

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“…Anionic,27, 28 cationic,29–31 and radical32–34 graft polymerizations on carbon black as well as functionalization of carbon black via dendrimer route16 were studied. Radical polymerizations can tolerate many functional groups and can be performed under mild conditions.…”

Section: Introductionmentioning

confidence: 99%

ATRP of butyl acrylates from functionalized carbon black surfaces

Liu

Casado-Portilla

Belmont

et al. 2005

J. Polym. Sci. A Polym. Chem.

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The functionalization of carbon black surface with atom transfer radical polymerization (ATRP) initiating sites and subsequent ATRP of n-butyl acrylate (n-BA) and t-butyl acrylate (t-BA) from the surface of carbon black is reported. The polymerizations were carried out using CuBr/N, N, N 0 , N@, N@-pentamethyldiethylenetriamine as the primary catalytic system in anisole at 70 8C. The initiator density on carbon black surface was tuned and the effect of initiator density on the polymers grafted on the surface was illustrated. Polymerizations were also performed in the presence of a sacrificial initiator to indirectly monitor the molecular weight evolution of polymers formed in the system. Block copolymerization of t-BA initiated from poly(n-BA) grafted carbon black was conducted to achieve water-dispersible carbon black composites after cleavage of the t-butyl groups. V V C 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4695-4709, 2005

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Grafting onto carbon black having few functional groups 7. Anionic graft polymerization from porous carbon black initiated by poly(potassium acrylate) retained in the pores.

Cited by 4 publications

References 0 publications

Grafting Poly(n-butyl acrylate) from a Functionalized Carbon Black Surface by Atom Transfer Radical Polymerization

Grafting Poly(n-butyl acrylate) from a Functionalized Carbon Black Surface by Atom Transfer Radical Polymerization

Modification of carbon black through grafting multihydroxyl hyperbranched polyether onto its surface

ATRP of butyl acrylates from functionalized carbon black surfaces

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