Investigating the network response to node removal and the efficacy of the node removal strategies is fundamental to network science. Different research studies have proposed many node centralities based on the network structure for ranking nodes to remove. The random walk (RW) on networks describes a stochastic process in which a walker travels among nodes. RW can be a model of transport, diffusion, and search on networks and is an essential tool for studying the importance of network nodes. In this manuscript, we propose four new measures of node centrality based on RW. Then, we compare the efficacy of the new RW node centralities for network dismantling with effective node removal strategies from the literature, namely betweenness, closeness, degree, and k-shell node removal, for synthetic and real-world networks. We evaluate the dismantling of the network by using the size of the largest connected component (LCC). We find that the degree nodes attack is the best strategy overall, and the new node removal strategies based on RW show the highest efficacy in regard to peculiar network topology. Specifically, RW strategy based on covering time emerges as the most effective strategy for a synthetic lattice network and a real-world road network. Our results may help researchers select the best node attack strategies in a specific network class and build more robust network structures.