Two-dimensional materials have gained a lot of research interest and found application in photovoltaics, photodetectors, sensors etc. owing to their exceptional properties such as electrical, optical, and mechanical which is dependent on layer thickness and crystallite size. In this present work molybdenum disulfide (MoS2)/graphene photodetectors were achieved by the hybridization of dispersive MoS2 and graphene. This was achieved with an innovative approach that improved the existing liquid phase exfoliation method in preparing highly dispersed heterostructure nanosheets of MoS2 and graphene in an IPA/water solvent. Furthermore, we achieved a vertically stacked MoS2/graphene photodetector and bare MoS2 photodetector in this study. The MoS2/Graphene hybrid nanosheets (MoS2/Gr NSs) were characterized using spectroscopic and microscopic techniques. The results obtained show the nanosheets have an average lateral size of 350-500 nm, with thickness ≤5 nm, and high crystallinity in the 2H semiconducting phase. The photocurrent, photoresponsivity, specific detectivity, and external quantum efficiency of MoS2/graphene heterostructure were 3.55 µA, 39.44 mA/W, 2.02×1010 Jones, and 7.54%, respectively, at 4V bias voltage, and that of MoS2 photodetector are 0.55 µA, 6.11 mA/W, 3.4 ×109 Jones, and 1.16%, respectively at 650 nm illumination wavelength. These results demonstrate that the photo-response performances of the as-prepared MoS2/Graphene NSs were greatly improved (about 7-fold) compared to that of sole MoS2 NSs. The results provide a simple, inexpensive and efficient method through sequential deposition technique for the fabrication of vertical heterojunctions with improved optoelectronic performance of heterostructure.