ZnMoO4/reduced graphene oxide composites (ZnMoO4/rGO) were successfully prepared by a simple one-pot hydrothermal method, in which the synthesis of ZnMoO4 irregular plate-like crystals and the reduction of graphene oxide to rGO were simultaneously achieved. The XRD, SEM, TEM, TGA and XPS measurements were performed to illustrate the structure properties of as-prepared ZnMoO4 and